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171.
Small amounts of felsic, evolved plutonic rocks, often called oceanic plagiogranites, always occur as veins or small stocks within the gabbroic section of the oceanic crust. Four major models are under debate to explain the formation of these rocks: (1) late-stage differentiation of a parental MORB melt, (2) partial melting of gabbroic rocks, (3) immiscibility in an evolved tholeiitic liquid, and (4) assimilation and partial melting of previously altered dikes. Recent experimental data in hydrous MORB-type systems are used to evaluate the petrogenesis of oceanic plagiogranites within the deep oceanic crust. Experiments show that TiO2 is a key parameter for the discrimination between different processes: TiO2 is relatively low in melts generated by anatexis of gabbros which is a consequence of the low TiO2 contents of the protolith, due to the depleted nature of typical cumulate gabbros formed in the oceanic crust. On the other hand, TiO2 is relatively high in those melts generated by MORB differentiation or liquid immiscibility. Since the TiO2 content of many oceanic plagiogranites is far below that expected in case of a generation by simple MORB differentiation or immiscibility, these rocks may be regarded as products of anatexis. This may indicate that partial melting processes triggered by water-rich fluids are more common in the deep oceanic crust than believed up to now. At slow-spreading ridges, seawater may be transported via high-temperature shear zones deeply into the crust and thus made available for melting processes.  相似文献   
172.
Analyses for 99Tc in some marine biological samples taken near the outlet of the low level radioactive effluent pipeline of the nuclear reprocessing plant of La Hague, France, gave positive results. From 500 to 3500 pCi kg?1 wet weight of 99Tc were observed in brown algae; Fucus sp. appeared to be a good indicator of this long-lived radionuclide in a marine environment.  相似文献   
173.
The influence of ablation cell geometry (Frames single‐ and HelEx two‐volume cells) and laser wavelength (198 and 266 nm) on aerosols produced by femtosecond laser ablation (fs‐LA) were evaluated. Morphologies, iron mass distribution (IMD) and 56Fe/54Fe ratios of particles generated from magnetite, pyrite, haematite and siderite were studied. The following two morphologies were identified: spherules (10–200 nm) and agglomerates (5–10 nm). Similarity in IMD and ablation rate at 198 and 266 nm indicates similar ablation mechanisms. 56Fe/54Fe ratios increased with aerodynamic particle size as a result of kinetic fractionation during laser plasma plume expansion, cooling and aerosol condensation. The HelEx cell produces smaller particles with a larger range of 56Fe/54Fe ratios (1.85‰) than particles from the Frames cell (1.16‰), but the bulk aerosol matches the bulk substrate for both cells, demonstrating stoichiometric fs‐LA sampling. IMD differences are the result of faster wash out of the HelEx cell allowing less time for agglomeration of small, low‐δ 56Fe particles with larger, high‐δ 56Fe particles in the cell. Even with a shorter ablation time, half the total Fe ion intensity, and half the ablation volume, the HelEx cell produced Fe isotope determinations for magnetite that were as precise as the Frames cell, even when the latter included an aerosol‐homogenising mixing chamber. The HelEx cell delivered a more constant stream of small particles to the ICP, producing a more stable Fe ion signal (0.7% vs. 1.5% RSE for 56Fe in a forty‐cycle single analysis), constant instrumental mass bias and thus a more precise measurement.  相似文献   
174.
We select 947 star-forming galaxies from SDSS-DR7 with [O III]λ4363emission lines detected at a signal-to-noise ratio larger than 5σ. Their electron temperatures and direct oxygen abundances are then determined. We compare the results from different methods. t2, the electron temperature in the low ionization region, estimated from t3, that in the high ionization region, is compared using three analysis relations between t2- t3. These show obvious differences, which result in some different ionic oxygen abundances. The results of t3, t2, O++/H+and O+/H+derived by using methods from IRAF and literature are also compared. The ionic abundances O++/H+are higher than O+/H+for most cases. The different oxygen abundances derived from Teand the strong-line ratios show a clear discrepancy, which is more obvious following increasing stellar mass and strong-line ratio R23. The sample of galaxies from SDSS with detected [O III]λ4363 have lower metallicites and higher star formation rates, so they may not be typical representatives of the whole population of galaxies. Adopting data objects from Andrews Martini, Liang et al. and Lee et al. data, we derive new relations of stellar mass and metallicity for star-forming galaxies in a much wider stellar mass range: from 106 M to 1011 M.  相似文献   
175.
Résumé Marcel Bertrand (1847–1907) est surtout connu pour avoir été le promoteur de la tectonique des grandes nappes alpines. Le présent article entend attirer l'attention sur un aspect moins souvent abordé de son oeuvre. En passant en revue et comparant, de façon à la fois méthodique et empirique, les données alors disponibles, il découvre une homologie frappante entre les suites d'évènements qui ont abouti à la formation des grandes chaînes de montagnes successives de l'Europe. Chacune a ses gneiss, son «Flysch fin» précoce, son «Flysch grossier» tardif externe et enfin ses grès rouges (molasses); de même, pour l'histoire magmatique et même métallogénique (roches vertes précoces, puis granite, «porphyres» et enfin laves basiques post-tectoniques). Il est donc clair que Marcel Bertrand a été le véritable initiateur (se gardant de tout dogmatisme), du modèle «programmé» de l'orogenèse, en général attribué à Hans Stille et ses é mules. D'un point de vue historique, on peut voir dans sa conception de l'orogenèse une synthèse réconciliant plusieurs théories jusque là antagonistes: l'étagement des grandes formations universelles de Werner devient le produit régionalement hétérochrone des cycles de transformation de Hutton; et les soulèvements successifs catastrophiques d'Elie de Beaumont sont retraduits en termes lyelliens, processus lents et graduels, néanmoins récurrents et ordonnés.
Marcel Bertrand (1847–1907) is best known for his trail-blazing recognition of the great nappes. The present paper draws attention to a lesser known side of his work: through a methodical, empirical review of the available data, Marcel Bertrand brought to light a striking similarity in the sequence of events which led to the formation of each of the successive mountain chains of Europe. Each has its own gneisses, early fine Flysch, later coarse external Flysch, and late red sandstone; and also the same magmatic (and even metallogenic) suite (early greenstones, then granite, porphyries, and finally post-tectonic basic lavas). Thus it appears that Marcel Bertrand was the real originator (avoiding any dogmatization) of the programmed model of orogeny commonly ascribed to Hans Stille and his followers. From a historical point of view, one may see in this conception of mountain building a conciliatory synthesis between some major antagonistic theories: the Wernerian universal formations become heterochronous products of the Huttonian cycle; and the catastrophic successive orogenies of Elie de Beaumont actually amount to slow, gradual, Lyellian processes, nonetheless orderly and recurrent.

Zusammenfassung Marcel Bertrand ist besonders als der Entdecker der großen Alpinen Überschiebungen bekannt. Hier wird eine weniger bekannte Seite seines Werkes erwähnt: er hat klargemacht, daß die verschiedenen europäischen Gebirgsketten eine parallele und strukturierte Geschichte haben (sedimentär, magamatisch, metallogenisch). Eine objektive Zusammenstellung der tatsächlichen Kenntnisse zeigt, daß jedes Orogen seine Gneise, seinen feinen Flysch in dem zentralen Trog, seinen groben Flysch am Rand und sein Rotliegendes als Späterscheinung hat. In jedem Fall erkennt man die Anwesenheit von basischen Gesteinen als Früherscheinungen, von Graniten, dann von Porphyren und am Ende von posttektonischen, basischen Gesteinen. Hier kann man das von H. Stille und seinen Nachfolgern entwickelte Schema erkennen, das aber hier bei M. Bertrand rein empirisch bleibt. Vom historischen Standpunkt her ist es möglich, das Werk von M. Bertrand als die Synthese, die Zusammenfassung verschiedener, bis dahin antagonistisch gestellter Strömungen zu betrachten: der Wernersche, stufenartige, theoretische Bau wird zur heterochronen Folge des Huttonschen Zyklus; die nacheinander sich entwikkelnden katastrophalen Orogenesen von Elie de Beaumont werden, wie bei Lyell, langsam aber dennoch strukturiert und wiederkehrend.

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  相似文献   
176.
Small mountain lakes are natural archives for understanding long-term natural and anthropogenic impact on the environment. This study focused on long-term (last ca. 13 000 years) vegetation changes and sedimentary processes in the catchment area of Lake Planina pri jezeru (1430 m a.s.l.) by using mineralogical, geochemical and palynological methods. Palynological results suggest that regional vegetation between 12 900 and 11 700 cal a bp was a herbaceous–forest tundra (Pinus, Artemisia, Poaceae ). Climate warming at the beginning of the Holocene (ca. 11 700 cal a bp ) caused the transition from a wetland (Cyperaceae) to an eutrophic lake with alternating anoxic (pyrite) and oxic conditions (gypsum). In addition, the surrounding area became forested (Picea, Larix, Ulmus). Fagus expanded at 10 200 cal a bp and Abies at 8200 cal a bp. Between 7500 and 4300 cal a bp , human impact on the environment was barely noticeable and mostly limited to grazing. During 4300–430 cal a bp human impact became more evident and gradually increased. The greatest influence was observed from 430 cal a bp onwards, when excessive exploitation of the surrounding area (logging and grazing) severely eutrophicated the lake.  相似文献   
177.
The effect of MgO and total FeO on ferric/ferrous ratio in model multicomponent silicate melts was investigated experimentally in the temperature range 1300–1500 °C at 1 atm total pressure in air. We demonstrate that the addition of these weak network modifier cations results in an increase of Fe3+/Fe2+ ratio in both mafic and silicic melts. Based on present and published experimental data, a new empirical equation is proposed to predict the ferric/ferrous ratio as a function of oxygen fugacity, temperature and melt composition. In contrast to previous equations, the compositional effect of melts on the Fe3+/Fe2+ ratio is not only modeled by the sum of the molar fraction of the individual oxide components. Additional interactions terms have also been incorporated. The main advantage of the proposed model is its applicability for a wide compositional range. However, its application to felsic melts (>?68 wt% SiO2) is not recommended. Other advantages of this equation and differences when compared with previous models are discussed.  相似文献   
178.
The study examines rupture of evaporating liquid bridges between two glass spheres. Evolution of the bridge profile has been recorded with the use of high-speed camera. Geometrical characteristics of the bridge were then used to calculate evolution of the variables during the process: Laplace pressure, capillary force, and surface tension force. For the purpose of reference, the bridge evolution is followed also during kinematic extension. During both processes the diameter of the neck decreases, with an acceleration of about 1–2 ms before the rupture. Two distinct rupture modes are observed, depending on the bridge aspect ratio. After the rupture, the mass of liquid splits, forming two separate oscillating drops attached to the spheres, and a suspended satellite droplet. Just before the rupture, an increasing repulsive Laplace pressure, and decreasing negative surface tension force develop. Capillary force follows the trend of the surface tension force, with an accelerating decline. Duration of the whole process and liquid mass stabilization is from 10 to 60 ms.  相似文献   
179.
180.
Measurements of benthic foraminiferal cadmium:calcium (Cd/Ca) have indicated that the glacial–interglacial change in deep North Pacific phosphate (PO4) concentration was minimal, which has been taken by some workers as a sign that the biological pump did not store more carbon in the deep glacial ocean. Here we present sedimentary redox-sensitive trace metal records from Ocean Drilling Program (ODP) Site 882 (NW subarctic Pacific, water depth 3244 m) to make inferences about changes in deep North Pacific oxygenation – and thus respired carbon storage – over the past 150,000 yr. These observations are complemented with biogenic barium and opal measurements as indicators for past organic carbon export to separate the influences of deep-water oxygen concentration and sedimentary organic carbon respiration on the redox state of the sediment. Our results suggest that the deep subarctic Pacific water mass was depleted in oxygen during glacial maxima, though it was not anoxic. We reconcile our results with the existing benthic foraminiferal Cd/Ca by invoking a decrease in the fraction of the deep ocean nutrient inventory that was preformed, rather than remineralized. This change would have corresponded to an increase in the deep Pacific storage of respired carbon, which would have lowered atmospheric carbon dioxide (CO2) by sequestering CO2 away from the atmosphere and by increasing ocean alkalinity through a transient dissolution event in the deep sea. The magnitude of change in preformed nutrients suggested by the North Pacific data would have accounted for a majority of the observed decrease in glacial atmospheric pCO2.  相似文献   
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